How it works
An electrolytic cell diagram for the electrolysis of molten sodium chloride. Start with the 4 main parts, then follow what moves and what is made.
Read the full guide
Follow the charges
The battery pushes electrons into the cathode, making it negative, and pulls them from the anode, making it positive. Positive sodium ions move to the cathode; negative chloride ions move to the anode.
What is made
At the anode, chloride ions lose electrons and chlorine gas bubbles off. At the cathode, sodium ions gain electrons and become liquid sodium metal.
- An Ox and a Red Cat: oxidation happens at the anode and reduction at the cathode, in every cell.
Questions and answers
Is the anode positive or negative in an electrolytic cell?
Positive. It is joined to the positive terminal of the power source. In a galvanic cell it is the other way round: the anode is the negative electrode.
What is the difference between an electrolytic cell and a galvanic cell?
A galvanic cell makes electricity from a reaction that happens on its own. An electrolytic cell uses electricity from outside to force a reaction that would not.
What does electrolysis of molten sodium chloride produce?
Chlorine gas at the anode and liquid sodium metal at the cathode. It is how both are made in industry.