How it works
This galvanic cell diagram shows a voltaic cell, the kind of electrochemical cell inside a battery: two half-cells joined by a salt bridge and a wire, with electrons flowing from anode to cathode.
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Two half-cells
At the anode, oxidation gives up electrons and the metal slowly dissolves into its half-cell. At the cathode, reduction takes electrons in and ions from its solution plate onto the metal.
Closing the loop
Electrons flow through the wire from anode to cathode, doing work on the way. The salt bridge lets ions flow between the solutions so neither builds up a charge that would stop the current.
- A way to remember: oxidation at the anode, reduction at the cathode. Both anode and oxidation begin with a vowel.
Questions and answers
What does the salt bridge do in a galvanic cell?
It is a tube of inert electrolyte joining the two solutions. Ions flow through it to balance the charge as the reaction runs; without it, the current would soon stop.
Which way do electrons flow in a galvanic cell?
Through the external wire from the anode, where oxidation releases them, to the cathode, where reduction uses them.
Is a galvanic cell the same as a voltaic cell?
Yes. Both names mean a cell that turns a spontaneous chemical reaction into electric current, like the cells in a battery.