How it works
This aufbau diagram worksheet is a blank orbital diagram worksheet to print: rows of empty boxes from 1s to 5p, rising in the order they fill, enough for any element up to xenon. Oxygen is filled in at the foot.
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Filling in the blank diagram
Count the element's electrons and draw one arrow for each. Start at the lowest row and work up, following the arrows of the diagonal rule: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p.
Three rules for the arrows
Lower rows fill first: the aufbau principle. A box holds two arrows at most, one up and one down: the Pauli exclusion principle. In a row of several boxes every box gets one arrow before any gets a second: Hund's rule.
- Chromium and copper are two of the elements whose real arrangement differs from the one the ladder predicts.
Questions and answers
What is an aufbau diagram?
A chart of an atom's sublevels drawn as rows of boxes in order of energy, lowest at the bottom. Electrons go in as arrows from the bottom up. Aufbau is German for building up.
What is the order of filling in an aufbau diagram?
1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, and then 6s. The 4s row fills before 3d, and 5s before 4d.
How many electrons fit in each sublevel?
An s sublevel has one orbital and holds 2 electrons. A p sublevel has three orbitals and holds 6. A d sublevel has five orbitals and holds 10.
What is Hund's rule?
In a sublevel with several orbitals, each orbital gets one electron before any gets a second, and the single electrons share the same spin. Oxygen's 2p row shows it: one pair and two single arrows.
Why does 4s fill before 3d?
In the filling order the 4s sublevel comes just below 3d in energy. The n + l rule gives the same answer: 4 + 0 is less than 3 + 2.